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Neutral and Anionic Monomeric Zirconium Imides Prepared via Selective C=N Bond Cleavage of a Multidentate and Sterically Demanding β‐Diketiminato Ligand

https://doi.org/10.1002/asia.201900451

Kurogi, Takashi; Chu, Jiaxiang; Chen, Yaofeng; Mindiola, Daniel J. (June 2019, Chemistry – An Asian Journal)

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Methylidyne Transfer Reactions with Niobium

https://doi.org/10.1021/acs.organomet.8b00245

Kurogi, Takashi; Pinter, Balazs; Mindiola, Daniel J. (June 2018, Organometallics)

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Well-Defined Titanium Complex for Free-Radical and Cationic Photopolymerizations under Visible Light and Photoinduction of Ti-Based Nanoparticles

https://doi.org/10.1021/acs.macromol.8b02719

Breloy, Louise; Brezová, Vlasta; Malval, Jean-Pierre; Rios de Anda, Agustin; Bourgon, Julie; Kurogi, Takashi; Mindiola, Daniel J.; Versace, Davy-Louis (May 2019, Macromolecules)

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Selenenate Anions (PhSeO ⁻ ) as Organocatalyst: Synthesis of trans ‐Stilbenes and a PPV Derivative

https://doi.org/10.1002/adsc.201901201

Zheng, Zhipeng; Trofymchuk, Oleksandra_S; Kurogi, Takashi; Varela, Elena; Mindiola, Daniel_J; Walsh, Patrick_J (December 2019, Advanced Synthesis & Catalysis)

Abstract The selenenate anion (RSeO⁻) is introduced as an active organocatalyst for the dehydrohalogen coupling of benzyl halides to formtrans‐stilbenes. It is shown that RSeO⁻is a more reactive catalyst than the previously reported sulfur analogues (sulfenate anion, RSO⁻) and selenolate anions (RSe⁻) in the aforementioned reaction. This catalytic system was also applied to the benzylic‐chloromethyl‐coupling polymerization (BCCP) of a bis‐chloromethyl arene to form ppv (poly(p‐phenylene vinylene))‐type polymers with high yields, M_n(average molecular weight) up to 13,000 and Đ (dispersity) of 1.15. magnified image
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